RT Report T1 Environmental Health Criteria 195 - Hexachlorobenzene A1 World Health Organization, A2 Newhook, R. A2 Dormer, W. K1 benzene K1 environmental health K1 toxic substance K1 environmental degradation PB World Health Organization SN 92 4 157195 0 YR 1997 FD 1997 LK https://wedocs.unep.org/handle/20.500.11822/29473 UL https://wedocs.unep.org/handle/20.500.11822/29473 NO Hexachlorobenzene (HCB) is a chlorinated organic compound with moderate volatility. It is practically insoluble in water, but is highly lipid-soluble and bioaccumulative. Technical grade HCB contains up to 2% impurities, most of which is pentachlorobenzene. The remainder includes the higher chlorinated dibenzo- p-dioxins, dibenzofurans and biphenyls. Analysis of HCB in environmental media and biological materials generally involves extraction of the sample into organic solvents, often followed by a clean-up step, to produce organic extracts for gas chromatography/mass spectrometry (GC/MS) or gas chromatography with electron capture detection (GC/ECD). DS UN Environment Document Repository RD Sep 21, 2026